Find the pH of the equivalence point and the volume(ml) of 0.125M HCl needed to reach the point in titrations of: a) 65.5ml of 0.234M NH3.b) 21.8 mL of 1.11 M CH3NH2.

Answers

Answer 1

Answer:

a. 122.6 mL / pH = 4.03

b. 193.6 mL / pH = 5.73

Explanation:

In the equivalence point we know: mmoles acid = mmoles base- And the pH in a titration between a weak base and a strong base, is acid, at the equivalence point. For the volume, we can replace the equation with the data given.

a. 0.125M . volume of acid = 65.5 mL . 0.234M

Volume of acid = (65.5 . 0.234) / 0.125 = 122.6 mL

Total volume at the equivalence point = 188.1 mL

b. 0.125M . volume of acid = 21.8 mL . 1.11 M

Volume of acid = (21.8 .  1.11) / 0.125 = 193.6 mL

Let's calculate the pH. In the equilavence point we have a neutralization reaction.

a. NH₃ + HCl → NH₄Cl

All the mmoles of protons (65.5 mL . 0.234M) react to ammonia, to obtain ammonium.

New concentration is: 15.32 mmoles / 188.1 mL = 0.0814 M

This is the [NH₄⁺] to determine the pH in the acid base equilibrium.

NH₄⁺  +  H₂O  ⇄  NH₃  +  H₃O⁺      Ka

Expression for Ka = [NH₃]  . [H₃O⁺] / [NH₄⁺]

5.6×10⁻¹⁰ = x² / (15.32 - x)

(We can avoid the quadratic equation 'cause Ka is so small)

√(5.6×10⁻¹⁰ . 15.32) = x → [H₃O⁺] = 9.26×10⁻⁵

pH = - log [H₃O⁺] → 4.03

b. CH₃NH₂ + HCl → CH₃NH₃Cl

All the mmoles of protons (21.8 mL . 1.11M) react to methylamine, to obtain methylammonium.

New concentration is: 24.2 mmoles / 193.6 mL = 0.125 M

This is the [CH₃NH₃⁺] to determine the pH in the acid base equilibrium.

CH₃NH₃⁺  +  H₂O  ⇄  CH₃NH₂  +  H₃O⁺      Ka

Expression for Ka = [CH₃NH₂]  . [H₃O⁺] / [CH₃NH₃⁺]

2.7×10⁻¹¹ = x² / (0.125 - x)

(We can avoid the quadratic equation 'cause Ka is so small)

√(2.7×10⁻¹¹ . 0.125) = x → [H₃O⁺] = 1.84×10⁻⁶

pH = - log [H₃O⁺] → 5.73

Answer 2

The pH of the equivalence point of 0.125M HCl with NH₃ is 4.03 and with CH₃NH₂ is 5.73.

What is equivalence point?

In the acid - base titration, at the equivalence point equal moles of acid as well as of base are present.

First we calculate the volume of HCl by using the below equation as:

M₁V₁ = M₂V₂, where

M₁ = molarity of NH₃ = 0.234 M

V₁ = volume of NH₃ = 65.5 mL

M₂ = molarity of HCl = 0.125 M

V₂ = volume of HCl = ?

V₂ =  (65.5 . 0.234) / 0.125 = 122.6 mL

Total volume at the equivalence point = 188.1 mL

Chemical reacion will be written as:

NH₃ + HCl → NH₄Cl

All moles of protons react with moles of ammonia, so new moles (n) will be calculated as:

n = molarity × volume

n = 65.5 mL × 0.234M = 15.32 moles

Now, concentration in terms of molarity will be 15.32 mmoles / 188.1 mL = 0.0814 M

pH in the acid-base reaction due to [NH₄⁺], as:

NH₄⁺  +  H₂O  ⇄  NH₃  +  H₃O⁺

Value of Ka for this reaction is = 5.6×10⁻¹⁰

According to the ICE table, Ka equation will be written as-

5.6×10⁻¹⁰ = x² / (15.32 - x)

x = [H₃O⁺] = 9.26 × 10⁻⁵

pH = - log [H₃O⁺] = 4.03

Again we calculate the volume of HCl with the CH₃NH₂ as:

0.125M . volume of acid = 21.8 mL . 1.11 M

Volume of acid = (21.8 .  1.11) / 0.125 = 193.6 mL

Total volume at the equivalence point = 215.4 mL

Chemical reacion will be written as:

CH₃NH₂ + HCl → CH₃NH₃Cl

All moles of protons react with moles of ammonia, so new moles (n) will be calculated as:

n = 21.8 mL . 1.11M = 24.2 moles

Now, concentration in terms of molarity will be 24.2 moles / 215.4 mL = 0.11M

pH in the acid-base reaction due to [CH₃NH₃⁺], as:

CH₃NH₃⁺  +  H₂O  ⇄  CH₃NH₂  +  H₃O⁺

Value of Ka = 2.7×10⁻¹¹

According to the ICE table, Ka equation will be written as-

2.7×10⁻¹¹ = x² / (0.11 - x)

x = [H₃O⁺] = 5.4×10⁻⁶

pH = - log [H₃O⁺] = 5.73

Hence the value of pH will be 4.03 and 5.73 respectively.

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Related Questions

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Answer:

A chemical reaction is the process in which atoms present in the starting substances rearrange to give new chemical combinations present in the substances formed by the reaction. These starting substances of a chemical reaction are called the reactants, and the new substances that result are called the products.

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Answer:

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Km/hr is a unit of expressing the speed of a body. Speed is the rate of change of distance with time. Also, the same unit is applicable for expressing the velocity of a body. But to find the velocity, we must emphasize the direction of motion of the body.

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Answers

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To find the amount of moles in a 10 g sample, we need the molar mass of ethanol.

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Now that we have the molar mass, we can find moles.

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Answers

Answer:

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Match Term Definition
Pure substance A) Liquid homogeneous mixture in which the solute is distributed evenly within the solvent
Heterogeneous B) Mixture that has its different components mixed evenly within the substance
Homogeneous C) Mixture that has its different components mixed unevenly within the substance
Solution D) Consists of a single element or type of compound

Answers

Answer:

b

Explanation:

this should help

PLEASE HURRY WILL GIVE BRAINLEST IF ANSWERED CORRECTLY
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Answers

Answer:

Evaporation is a technique used to separate out homogeneous mixtures where there is one or more dissolved salts.

Explanation:

Hope this helps :)

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Answers

Answer:

Volume of water added = 148.4 mL

Explanation:

Given data:

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Volume of water added = ?

Solution:

Formula:

M₁V₁  =   M₂V₂

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Answer:

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Question:

How are changes of state different from chemical change?

Answer:

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Answer:

Chemical change happens when a substance changes they molecular structure, it often involves change in color (rusting iron), transfer of energy (copper smelting), or gas bubbling.

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Answers

Answer:

Explanation:

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Melting point: Water melts/freezes at 801 °C

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Separating technique: It's component cannot be separated by physical means

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Melting point: It melts at about 37 °C

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A pure substance is an homogeneous material, having a composition, and

properties that are consistent through out the material.

The chemical properties of a pure substance are defined, such as the

products of its reaction can be predictable.

A chemical is pure when it consist of a single type of particle such as an

element, a molecule or a compound.

The five pure substances are presented as follows;

[tex]\displaystyle\begin{tabular}{|l|l|l|l|l|}\underline{Pure \ Substances}&\underline{Appearance}&\underline{Separaing Tech}&\underline{Boiling \ Point}&\underline{Melting \ point}\\1. Diamond&Translucent \ solid&Inseparable&3550^{\circ}&4830^{\circ}\\2. Table \ salt&White\ crystals&Insepble&801^{\circ}&1413^{\circ}\\3. Water&Tran parent \ liquid&Insepble&0^{\circ}&100^{\circ}\\4. Sugar&Whilte \ crystals&Heating&Decomposes&186^{\circ}\\5. Gold&Yellowish \ metal&Inseparable& 2700^{\circ}&1064^{\circ}\end{array}[/tex]

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Answers

Answer:

[tex]v=6.7\times 10^9\ mi/hr[/tex]

Explanation:

Given that,

The speed of light is 3×10⁸ m/s

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Answer:

the density of CO2 gas at STP is 1.96 g/l.

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Answer:

Examples of ROS include peroxides, superoxide, hydroxyl radical, singlet oxygen, and alpha-oxygen.

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Answer:

Ammonia is moderately a base

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Submit Test
Question 10 of 12- POS
GR8 Sci U03 USA FY21 Question: 1-10
Hannah added a silvery white metal to a beaker of cold water and noticed that gas bubbles were given off and a different substance formed. When she repeated the activity with hot water she noticed the gas bubbles were
released much more rapidly. Which statement best explains why the reaction occurred faster in hot water?
M

Answers

The correct answer is Hot water increases the collision rate of molecules, causing the reaction to occur faster.

Explanation:

Temperature is directly related to the kinetic energy or movement of molecules in a substance. In this context, a higher temperature leads to more kinetic energy or more collision between molecules. At the same time, a chemical reaction involves molecules of two or more substances colliding and creating bonds to form new substances. This implies an increase in temperature means molecules colliding faster, new substances forming in a shorter time, and therefore a faster chemical reaction. According to this, the first answer is correct.

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Answers

Answer:

Pumps also called transporters, are transmembrane proteins that actively move ions and/or solutes against a concentration or electrochemical gradient across biological membranes.

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Answers

Answer:

Atoms in group 2a are likely to form ions with a +2 charge because they have two valence electrons, both of which experience a very weak pull from the nucleus due to electron shielding. This causes the atoms to be easily pulled away from the nucleus, creating the +2 ions we see in nature.

Atoms in group 7a are likely to form ions with a -1 charge because they are one electron away from completing their outermost shell. The large number of protons in the middle of these atoms also causes the valence electrons to experience a stronger net force. This force also pulls strongly on the valence electrons of other atoms, causing the -1 ions we see in nature.

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Answers

Answer:

Convection currents are caused by a temperature difference in gases and liquids. As one area becomes warmer than another the molecules have more energy and start vibrating more vigorously thus spreading out and becoming less dense. This means that the less dense parts will become more buoyant causing them to rise.

Explanation:

Answer:

Convection currents are caused by a temperature difference in gases and liquids.  

Explanation:

As one area becomes warmer than another the molecules have more energy and start vibrating more vigorously thus spreading out and becoming less dense. This means that the less dense parts will become more buoyant causing them to rise.

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A.Sugar
B.Salt
C.Urea
D.Urine

Answers

D, Urine.

Just google what sweat is made of and it gives you all of the answers except for urine. Also you’d probably smell really bad if your sweat had urine in it. Hope this helps! :)

Which statement best describes why a chemical property change is different from a physical change?

A. A chemical change results in a different state of matter; and a physical change results in a new substance being formed.

B. A chemical change results in a new substance being formed; whereas, a physical change will result in a different state of matter.

C. A chemical change is used by scientists to create new substances, and a physical change happens naturally.

D. A chemical change is used to identify characteristics of a substance, and a physical change identifies the behavior of a substance when in a reaction.

Answers

Answer:

B

Explanation:

a chemical change is making a new substance and physical change with a result in a different state of matter:)

A gas sample in a balloon contains 4.0 moles of gas at a particular pressure, volume and temperature. If your balloon springs a leak and the volume decreases to 1/2 of the original amount before you can plug the leak, how many moles of gas have you lost (temperature and pressure remain the same)?

Answers

Answer:

Explanation:

When volume of gas is V , pressure is P and temperature is T , if n be number of moles of gas

PV / RT = n , R is universal gas constant .

When volume becomes .5 V , pressure P and temperature T

number of moles = Px .5 V / RT = .5 PV / RT = .5 n

Number of moles of gas becomes half .

so 4 moles becomes  2 moles

No of moles lost = 4 - 2 = 2 moles.

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Answers

Answer:

b. cannot exist in optically active form

Explanation:

Stereochemistry is a branch of chemistry that involves the spatial arrangement of the atoms of molecules and studies how this affects the physical and chemical properties of such species.

The correct structure for (2R,3S)‑2,3‑dibromobutane can be seen in the image attached below. Since the compound is a meso compound due to the plane of symmetry. Thus, the compound is achiral. i.e. Compounds that are superimposable on its mirror image. The plane of symmetry is vertical inclined at 90°(i.e. perpendicular) to the page thus goes via the middle of the molecule.

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