2. Write down the assignments for the two lowest energy visible absorption bands in the following molecules. a) [Rh(OH2)6]2+ c) [Re Cls] b) [Fe(CN6]

The substituent refers to the atom or group that replaces hydrogen atom or carbon.

Isomer is the structurally different compound comprising same molecular formula. Ionic is the chemical bond holding together ions. Neutral replacement requires replacement with same charge or mass depending on the context.

The correct option substituent holds property to influence the chemical characteristics and it can be an atom or functional group. The examples of substituents are carbonyl groups, halogens, hydroxyl, amino groups and others.

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The exact size of an atom is difficult to determine because the electrons in an atom are constantly moving and do not have a precisely defined position at any given moment.

In fact, according to the Heisenberg uncertainty principle, it is impossible to simultaneously determine the exact position and momentum of an electron.

The size of an atom is typically defined by its atomic radius, which is the distance from the nucleus to the outermost electron shell.

However, because electrons occupy a three-dimensional region of space known as an orbital, the atomic radius is not a fixed distance but rather a statistical estimate of the most likely distance an electron will be from the nucleus.

This means that the size of an atom can vary depending on the method used to measure it and the definition of "size" being used.

Additionally, the size of an atom can be influenced by external factors such as temperature and pressure, which can cause the electrons to move farther away or closer to the nucleus.

As a result, determining the exact size of an atom can be a complex and challenging task, and the measured size can only be an approximation.

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The primary structure of a protein is most important because the sequence of the amino acids determines its overall shape, function, and properties.                                                                                                                                                  

The primary structure is the linear sequence of amino acids that make up the protein and is crucial in determining how the protein folds into its three-dimensional structure. The sequence of amino acids also determines the protein's function and properties, such as its ability to bind to other molecules or catalyze chemical reactions. Understanding the primary structure is essential for understanding the overall structure and function of a protein.
The primary structure consists of a specific order of amino acids, which are the building blocks of proteins. This sequence dictates how the protein will fold and interact with other molecules, ultimately determining its biological function.

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At a temperature approximately 4.41 Kelvin, 4.51 moles of F2 gas would have a pressure of 248 Torr in a 5.00 L tank.

The Ideal gas law states that "the pressure multiplied by volume is equal to moles multiply by the universal gas constant multiply by temperature.

It is expressed as;

PV = nRT

Where P is pressure, V is volume, n is the amount of substance, T is temperature and R is the ideal gas constant ( 0.08206 Latm/molK ).

Given that:

Amount of gas n = 4.51 mol

Pressure P = 248 Torr = 248/760 atm = 31/95 atm

Volume of the gas V = 5.00 L

Temperature T = ?

Plug these values into the above formula and solve for temperature:

[tex]PV = nRT\\\\T = \frac{PV}{nR} \\\\T = \frac{\frac{31}{95}\ * \ 5 }{4.51 \ * \ 0.08206 } \\\\T = 4.41 \ K[/tex]

Therefore, the temperature of the gas is approximately 4.41 Kelvin.

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The IUPAC name of the compound shown is methyl propyl ether.

The compound consists of a methyl group (CH3) attached to the oxygen atom, and a propyl group (C3H7) attached to the other side of the oxygen atom. According to the IUPAC naming rules, when naming ethers, the alkyl groups attached to the oxygen atom are named alphabetically. In this case, the methyl group is named first, followed by the propyl group. Therefore, the correct IUPAC name for the compound is methyl propyl ether.

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Large crystals with well-formed crystal faces tend to form when the conditions for crystal growth are optimal. These conditions include slow cooling of a magma or solution, low concentration of impurities, and low rates of crystal growth.

When these conditions are met, atoms in the solution or magma can arrange themselves into a repeating crystal lattice structure. The slow cooling allows the atoms to arrange themselves in an orderly fashion, while low impurity concentration prevents distortion of the crystal lattice. Low rates of growth allow the crystal to develop and expand without any interference or interruption. These ideal conditions allow the crystal to form with large sizes and well-formed faces.
Large crystals with well-formed crystal faces tend to form when the cooling process of a magma or mineral-rich solution is slow and undisturbed. This allows the atoms to arrange themselves in a highly ordered, repetitive pattern, creating a crystalline structure. As more atoms join the crystal lattice, the crystal grows in size and develops its characteristic shape. The slow cooling allows ample time for the crystal to reach its full potential, resulting in large, well-formed crystals with defined faces.

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Among the given radicals, R3C is the most stable radical, while CH3 is the least stable radical.

Stability of radicals is influenced by factors such as electron delocalization, hyperconjugation, and steric hindrance. In this case, R3C (tertiary radical) is the most stable radical due to the presence of three alkyl groups attached to the carbon atom. The alkyl groups provide electron-donating inductive effects and allow for efficient electron delocalization, which stabilizes the radical.

On the other hand, CH3 (methyl radical) is the least stable radical. It has only one alkyl group attached to the carbon atom, limiting the electron-donating inductive effects and electron delocalization. As a result, the methyl radical is less stable compared to the other radicals provided.

RCH2 (secondary radical) and R2CH (primary radical) have intermediate stability between R3C and CH3. The number of alkyl groups attached to the carbon atom affects the stability, with more alkyl groups providing greater stabilization through electron delocalization.

Therefore, among the given radicals, R3C is the most stable radical, while CH3 is the least stable radical.

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The number of molecules per cubic meter (m³) in an ideal gas at standard temperature and pressure (STP) is approximately 2.69 x 10²⁵  molecules/m³.

The number of molecules per cubic meter (m³) in an ideal gas at standard temperature and pressure (STP) is approximately 2.69 x 10²⁵ molecules/m³.

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This substance falls under the category of an unsaturated fatty acid. A lengthy hydrocarbon chain attached to a carboxylic acid group makes up fatty acids, which are organic molecules. Fatty acid hydrocarbon chains can range in length and saturation level.

Unsaturated fatty acids have one or more double bonds between the carbon atoms, while saturated fatty acids have single bonds between the carbon atoms in the hydrocarbon chain.

The double bond between the 6th and 7th carbon atoms in the hydrocarbon chain makes the chemical in issue, CH3(CH2)5CH=CH(CH2)7COOH, an unsaturated fatty acid. The substance, which can also go by the names palmitoleic acid or hexadecenoic acid, is present in several plant and animal oils.

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The total pressure in the container is 49.3 atmospheres .

So, the correct answer is C.

The total pressure of a container can be calculated using the Ideal Gas Law:

PV = nRT

where P is pressure, V is volume, n is the number of moles, R is the gas constant (0.0821 L atm/mol K), and T is the temperature in Kelvin.

For a 10.0 L container with 10 moles of nitrogen gas and 10 moles of oxygen gas at 300 K, the total moles (n) is 20 moles.

Using the Ideal Gas Law:

P(10.0 L) = (20 mol)(0.0821 L atm/mol K)(300 K).

Solving for P, we get P = 49.3 atm.

Hence, the answer of the question is C.

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The hybridization of an atom refers to the type of orbitals that are used in the bonding process.

The hybridization of an atom refers to the type of orbitals that are used in the bonding process. In the indicated nitrogen atoms, the hybridization can be determined based on the number of bonded atoms and lone pairs. For option A, the nitrogen atom has only two bonded atoms, indicating that it is sp hybridized. In option B, the nitrogen atom has three bonded atoms, indicating sp2 hybridization. For option C, both nitrogen atoms have two bonded atoms and a lone pair, indicating sp2 hybridization. Finally, in option D, both nitrogen atoms have three bonded atoms and a lone pair, indicating sp3 hybridization. Overall, hybridization is an important concept in chemistry that helps to explain the geometry and stability of molecules. By understanding the hybridization of different atoms, we can better understand the properties and behavior of chemical compounds.

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To determine the molecular formula of carvone, we can use the given information that it has a mass of 150 in its mass spectrum, three double bonds, and one ring.

First, we need to calculate the total number of hydrogen atoms in carvone. Each double bond contributes two fewer hydrogens than a single bond, and the ring does not affect the hydrogen count. Therefore, the total number of hydrogen atoms can be calculated as (2 × 3) - 2 = 4.

Next, we need to determine the number of carbon atoms. Since carvone is a ketone, it contains a carbonyl group (-C=O). The carbon in the carbonyl group is not part of the ring or the double bonds. So, the number of carbon atoms can be calculated as (molecular mass - number of hydrogens) / 12 = (150 - 4) / 12 = 12.

Finally, we can construct the molecular formula using the calculated number of carbon and hydrogen atoms. Therefore, the molecular formula of carvone is C12H14.

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Answer:

Explanation:

Iron (Fe) is a common element that is found in the human body and is essential for the formation of red blood cells Cells are the basic building blocks of life and are found in all living organisms Air is a mixture of gases that is essential for life and contains oxygen which is required for the process of respiration

Iron (Fe) also plays a role in iron-air batteries where the power comes from the interaction of iron with oxygen. The steel oxidizes nearly exactly as it would during its corrosion phase within that procedure. The oxygen necessary for the reaction may be taken from the ambient air, eliminating the requirement for the cell to store it

To find the new density of the brass cylinder hanging in salt water, you can use the concept of apparent weight. Apparent weight is the weight of an object when it is submerged in a fluid, and it is equal to the actual weight minus the buoyant force.                                                                                                                                                                            

The buoyant force is the force exerted by the fluid on the object, which is equal to the weight of the displaced fluid.
So, to find the new density of the brass cylinder, you would first measure its apparent weight when it is submerged in salt water. Then, you can use the equation for apparent weight to calculate the buoyant force and subtract it from the actual weight of the brass cylinder.
Once you have the actual weight and the apparent weight, you can use the equation for density to find the new density of the brass cylinder in salt water. Density is the mass per unit volume of an object, so you would need to measure the volume of the brass cylinder as well.Buoyant force can be found by calculating the weight of the displaced saltwater volume, which is equal to the volume of the submerged brass cylinder.

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The commonly used types of laboratory glassware are pipettes and funnels. The correct option is Pipettes and funnels.

Tubing is not typically considered a type of laboratory glassware.

Pipettes are used for precise measurement and transfer of liquids. They come in various forms, such as volumetric pipettes, graduated pipettes, and micropipettes, allowing for accurate dispensing of specific volumes.

Funnels, on the other hand, are used for guiding liquids or fine-grained substances into containers with small openings. They aid in controlled pouring and prevent spillage or contamination during transfers.

Therefore, the correct option is: Pipettes and funnels.

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To determine the molar solubility of nickel(II) hydroxide (Ni(OH)2) in 0.20 M NaOH at 25 degrees Celsius, we need to consider the effect of the added NaOH on the solubility equilibrium.

The solubility of nickel(II) hydroxide can be represented by the following equilibrium equation:

Ni(OH)2 (s) ⇌ Ni2+ (aq) + 2OH- (aq)

The solubility product expression for this equilibrium is given as:

Ksp = [Ni2+] [OH-]^2

Given that the molar solubility of nickel(II) hydroxide in pure water is 4.1 x 10^-6 mol/L, we can represent this as:

[Ni2+] = x

[OH-] = 2x

Substituting these expressions into the solubility product expression, we have:

Ksp = (x) (2x)^2 = 4x^3

At equilibrium, the value of Ksp remains constant regardless of the presence of other ions. Therefore, the value of Ksp in pure water is equal to the value of Ksp in the presence of NaOH.

Now, we can consider the effect of adding 0.20 M NaOH. NaOH dissociates in water to form Na+ and OH- ions. The concentration of OH- ions contributed by the NaOH is 0.20 M.

To account for the contribution of OH- ions from NaOH, we add this concentration to the concentration of OH- derived from the nickel(II) hydroxide dissolution. Therefore, the concentration of OH- ions in the equilibrium expression becomes 2x + 0.20.

Now we can set up the equilibrium expression:

Ksp = (x) (2x + 0.20)^2

Substituting the value of Ksp (which remains constant) and solving for x, we can find the molar solubility of nickel(II) hydroxide in 0.20 M NaOH.

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All of these directly or indirectly determines the transition temperature.(option,e). The transition temperature of a lipid bilayer is influenced by multiple factors, all of which are listed options.

The ability of lipid molecules to be packed together plays a crucial role in determining the transition temperature.

Lipid molecules with shorter fatty acid chains are more fluid and have lower transition temperatures compared to those with longer chains, as shorter chains allow for increased mobility and reduced packing.

The saturation level of fatty acid chains also affects the transition temperature. Saturated chains pack tightly, leading to higher transition temperatures, while unsaturated chains, with double bonds, introduce kinks that disrupt packing, resulting in lower transition temperatures.

The extent of double bonds in the fatty acid chains affects the fluidity of the lipid bilayer. More double bonds introduce greater fluidity and lower transition temperatures.

Therefore, all of these factors contribute to the determination of the transition temperature, highlighting the complex interplay between lipid structure and membrane properties.

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To solve this problem, we can use the first law of thermodynamics:ΔU = Q - W, where ΔU is the change in internal energy, Q is the heat transferred, and W is the work done on the gas.

Given information:

n = 3.65 mol (number of moles)

V₁ = 0.1210 m³ (initial volume)

V₂ = 0.750 m³ (final volume)

P₁ = 1.00 atm (initial pressure)

To find the initial and final temperatures, we can use the ideal gas law:

P₁V₁ = nRT₁  [Initial state]

P₂V₂ = nRT₂  [Final state]

where R is the ideal gas constant.

Rearranging the equations to solve for temperature:

T₁ = P₁V₁ / (nR)

T₂ = P₂V₂ / (nR)

Substituting the given values, we get:

T₁ = (1.00 atm)(0.1210 m³) / (3.65 mol)(R)

T₂ = (1.00 atm)(0.750 m³) / (3.65 mol)(R)

The change in internal energy (ΔU) can be calculated using the equation:

ΔU = (3/2)nR(T₂ - T₁)

Substitute the known values to calculate ΔU.

The heat lost by the gas (Q) in an adiabatic process is zero because there is no heat transfer.

Q = 0

The work done on the gas (W) can be calculated using the equation:

W = ΔU - Q

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The answer is Option 3. There will be 3 oxygen atoms in the product. When two oxygen atoms from the substance with 2 oxygen atoms combine with one oxygen atom from the substance with 1 oxygen atom, they will form one water molecule, which has 3 oxygen atoms.

The product formed by the combination of the two substances will always have 3 oxygen atoms, regardless of the number of oxygen atoms in the individual substances.  So, the product of the reaction between the two substances will always contain 3 oxygen atoms, regardless of the number of oxygen atoms in the individual substances.

This is because the reaction forms a compound that has a specific composition, and the number of atoms in the compound is determined by the reactants and the chemical reaction that takes place. When two or more substances react, they can form new compounds with different properties than the original substances. In this case, if two substances with oxygen atoms react, they can form a compound that contains oxygen atoms.

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Correct Question:

A substance with 2 oxygen atoms is combined with a substance with 1 oxygen atom to form one product. What is true of the product?

Select one:

1. There will be no oxygen in the product.

2. Some of the oxygen will evaporate into the air.

3. There will be 3 oxygen atoms in the product.

4. There will be 6 oxygen atoms in the product

In the given spontaneous reaction:

3Ce4+(aq) + Cr(s) → 3Ce3+(aq) + Cr3+(aq)

The process that occurs at the cathode (the electrode where reduction takes place) is:

Reduction of Ce4+(aq)

Ce4+(aq) is being reduced to Ce3+(aq) at the cathode. Reduction involves the gain of electrons, and in this reaction, Ce4+ ions are gaining electrons to form Ce3+ ions.

Therefore, the reduction of Ce4+(aq) is the process that occurs at the cathode in this galvanic cell.

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To determine the approximate strain energy per CH2 for cyclopropane, we need to compare its heat of combustion per CH2 with that of an acyclic alkane with the same number of carbon atoms.

Cyclopropane is a cyclic molecule, and its strain energy arises from the angle strain caused by the bond angles being forced to deviate from the ideal tetrahedral angle of 109.5 degrees.

From the given table, the heat of combustion per CH2 for various acyclic alkanes are as follows:

- Methane (CH4): 1696 kJ

- Ethane (C2H6): 686 kJ

- Propane (C3H8): 664 kJ

The heat of combustion per CH2 decreases as the size of the alkane increases.

This decrease is due to the increase in the number of available carbon-carbon single bonds, which are stronger and more stable than carbon-hydrogen bonds.

Cyclopropane, having three carbon atoms, can be compared to propane (C3H8), which also has three carbon atoms.

Since both molecules have the same number of carbon atoms, we can approximate the strain energy per CH2 for cyclopropane by comparing their heat of combustion per CH2 values.

From the table, the heat of combustion per CH2 for propane is 664 kJ. Therefore, we can approximate the strain energy per CH2 for cyclopropane as approximately 664 kJ.

The closest option in the provided choices is:

c. 110 kJ

Please note that the given options may not accurately match the calculated value.

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Angiotensin -I (A-I) is a peptide hormone that is produced from the proteolytic action of renin on angiotensinogen. In order for A-I to become its active form, angiotensin -II (A-II), it must be subjected to the action of an enzyme known as angiotensin -converting enzyme (ACE).

Correct option is A.

ACE is a dipeptidyl carboxypeptidase that cleaves the terminal dipeptide from A-I, leaving the active form of A-II. This process is important because A-II is a potent vasoconstrictor that also stimulates aldosterone secretion from the adrenal cortex.

Aldosterone helps to regulate sodium and water balance in the body, and thus A-II plays a key role in maintaining normal blood pressure and fluid balance in the body. Therefore, ACE is necessary for the transformation of A-I into A-II, and without it the body would be unable to produce the active form of the hormone.

Correct option is A.

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Answer:

The formula to calculate the number of liters of a solution is:

(volume of solution) = (amount of solute) / (molarity)

where

(amount of solute) = 2.5 moles

(molarity) = 2.0 M

Plugging in the values:

(volume of solution) = (2.5 moles) / (2.0 M)

(volume of solution) = 1.25 L

Therefore, 1.25 liters of solution can be produced from 2.5 moles of solute if a 2.0M solution is needed.

Two molecules of water ([tex]H_2O[/tex]) are produced as the products of the reaction.  

In the chemical reaction 2[tex]H_2[/tex] + [tex]O_2[/tex] -> 2([tex]H_2O[/tex]), two molecules of hydrogen and one molecule of oxygen react to form two molecules of water.

The balanced equation for this reaction is:

2[tex]H_2[/tex] + [tex]O_2[/tex]  ----> 2([tex]H_2O[/tex])

The number of product molecules in this reaction is equal to the number of reactant molecules that are consumed in the reaction. In this case, there are two molecules of hydrogen [tex]H_2[/tex] and one molecule of oxygen in the reactant list, so two molecules of hydrogen and one molecule of oxygen are consumed in the reaction.

Therefore, two molecules of water (([tex]H_2O[/tex])) are produced as the products of the reaction.  

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The oxalate concentration in the unknown solution is not accurate because the amount of sodium oxalate used to prepare the solution was not measured exactly.

Discrepancies between bottles of solution can also introduce errors, making it difficult to determine the true concentration of the oxalate. Therefore, the oxalate concentration reported in the solution may not be accurate and could vary from bottle to bottle. The accuracy of the oxalate concentration in the unknown solution cannot be determined based on the information provided.

The amount of sodium oxalate used to prepare the solution was not measured, and discrepancies between bottles of solution can also introduce errors. Therefore, it is not possible to determine the true concentration of the oxalate in the solution, and any reported concentration may not be accurate. This is because different amounts of sodium oxalate could have been used in the preparation of different bottles of the solution, leading to variations in the concentration of the oxalate.  

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The given options, option D) with 2 dots on N and 6 dots on O would be the correct electron dot structure for OCN- with a formal charge of -1 on the most electronegative atom (oxygen).

To determine the electron dot structure for OCN- with a formal charge of -1 on the most electronegative atom, we need to calculate the formal charges for each atom in the molecule.

The electron dot structure for OCN- is:

O       C       N

. .      .       .

: O : . : C : : N :

' ' ' '

: '

. '

In this structure, oxygen (O) is the most electronegative atom, so we want it to have a formal charge of -1.

To determine the electron dot structure with a formal charge of -1 on the most electronegative atom (the atom with the highest electronegativity), we need to compare the electronegativities of the atoms in the OCN- molecule.

In the OCN- molecule, we have oxygen (O), carbon (C), and nitrogen (N). Oxygen is the most electronegative atom, followed by nitrogen and then carbon.

Looking at the given options:

A) 6 dots on N & 2 on O

B) 6 dots on N & 2 on C

C) 4 dots on N & 4 on O

D) 2 dots on N & 6 on O

We want to maximize the number of dots on the oxygen atom (O) and minimize the number of dots on the nitrogen atom (N) to give oxygen a formal charge of -1. The correct option would be the one with the most dots on oxygen and the fewest dots on nitrogen.

Among the given options, option D) with 2 dots on N and 6 dots on O would be the correct electron dot structure for OCN- with a formal charge of -1 on the most electronegative atom (oxygen).

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When C2H5OH (ethanol) and O2 (oxygen) combust, the two products produced are CO2 (carbon dioxide) and H2O (water).

The balanced chemical equation for the combustion of ethanol can be written as:

C2H5OH + 3O2 → 2CO2 + 3H2O

This equation shows that one molecule of ethanol (C2H5OH) reacts with three molecules of oxygen (O2) to produce two molecules of carbon dioxide (CO2) and three molecules of water (H2O).

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You should add approximately 6.42 grams of solid magnesium chloride to prepare a 0.135 M aqueous solution in a 500 ml volumetric flask.

To make an aqueous solution of 0.135 M magnesium chloride in a 500 ml volumetric flask, you need to determine the amount of solid magnesium chloride required.

First, let's understand the relationship between molarity, moles, and volume of the solution:

Molarity (M) = Moles of solute / Volume of solution (in liters)

Since we want to prepare a 0.135 M solution, we need to determine the moles of magnesium chloride (MgCl2) required.

Moles of MgCl2 = Molarity × Volume of solution (in liters)

Volume of solution = 500 ml = 500/1000 = 0.5 liters

Moles of MgCl2 = 0.135 M × 0.5 liters = 0.0675 moles

To calculate the mass of solid magnesium chloride needed, we'll use its molar mass:

Molar mass of MgCl2 = 24.31 g/mol + 2(35.45 g/mol) = 95.21 g/mol

Mass of MgCl2 = Moles of MgCl2 × Molar mass of MgCl2

Mass of MgCl2 = 0.0675 moles × 95.21 g/mol ≈ 6.42 grams

Therefore, you should add approximately 6.42 grams of solid magnesium chloride to prepare a 0.135 M aqueous solution in a 500 ml volumetric flask.

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There are 6 attomoles of epinephrine in each vesicle.

The number of molecules per vesicle is 3.613 * 10¹⁵ molecules

The volume of the vesicle is 3.35 * 10⁻¹⁸ m³ or 3.35 * 10⁻¹⁵ L

The molar concentration of epinephrine in the vesicle is 2.99 M.

The number of attomoles of epinephrine in each vesicle is determined as follows:

Number of attomoles per vesicle = (150 fmol / 2.5 x 10⁴) / 10⁹

Number of attomoles per vesicle = 6 amol

(b) To find the number of molecules of epinephrine in each vesicle is determined as follows:

Molecular weight of epinephrine = 183.2 g/mol

Based on Avogadro's number:

1 mole of epinephrine = 6.022 * 10²³ molecules

1 amol of epinephrine = 6.022 * 10¹⁴ molecules

Number of molecules per vesicle = 6 * 6.022 * 10¹⁴

Number of molecules per vesicle = 3.613 * 10¹⁵ molecules

(c) The volume of a vesicle with radius r is:

r = 200 nm or 2 * 10⁻⁷ m, we get:

V = (4/3) * π * (2 * 10⁻⁷)³

V = 3.35 * 10⁻¹⁸ m³

Converting to liters:

1 L = 10⁻³ m³

The volume of the vesicle in liters will be:

V = 3.35 * 10⁻¹⁸ m³ * (1 / 10⁻³)

V = 3.35 * 10⁻¹⁵ L

(d) The molar concentration of epinephrine in the vesicle is determined using the formula below:

Molar concentration = 10 amol / 3.35 * 10⁻¹⁸ m³

Converting amol to mol:

Molar concentration = 10 * 10⁻¹⁸ mol / 3.35 * 10⁻¹⁸ m³

Molar concentration = 2.99 M

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Among the given options, (c) 100 °C and 0.5 atm would cause a gas to exhibit the least deviation from ideal gas behavior. The conditions that cause a gas to exhibit the least deviation from ideal gas behavior are high temperatures and low pressures.

This is because at high temperatures, the gas molecules have more kinetic energy and move around more rapidly, and at low pressures, the gas molecules are more spread out and experience weaker intermolecular forces.

At high pressures, the gas molecules are closer together and can interact more strongly, which can lead to deviations from ideal gas behavior. Similarly, at low temperatures, the gas molecules have less kinetic energy and move around more slowly, which can also lead to deviations from ideal gas behavior.

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